Graphene oxide doped ethanol droplet combustion: Ignition delay and contribution of atomization to burning rate

TL;DR

This study experimentally investigates how graphene oxide doping and oxidation levels affect ethanol droplet ignition delay and burning rate, revealing that doping generally enhances burning rate while atomization can suppress mass loss.

Contribution

It provides new insights into the effects of graphene oxide doping and oxidation levels on ethanol droplet combustion, including atomization behavior and burning rate enhancement.

Findings

Increasing graphene oxide loading generally increases ignition delay.

Doping with highly oxidized graphene oxide can reduce ignition delay.

Maximum burning rate enhancement of 8.4% observed with reduced graphene oxide at 0.1% loading.

Abstract

Effects of graphene oxide nanomaterials addition and oxidation level on ignition delay and burning rate of ethanol droplets are experimentally investigated. Three graphene oxide samples are synthesized and characterized. Separate high-speed OH* chemiluminescence and high-speed shadowgraphy images are collected. The results suggest that increasing the loading concentration from 0 to 0.1% generally increases the ignition delay, except for ethanol doped with the highly oxidized graphene. The probability density function of the atomized baby droplet diameter, initial projected velocity, and length of the projected trajectory are similar for all tested conditions and independent of the oxidation level and loading concentration of the additives. The joint probability density function calculated for the atomization-related parameters against one another suggests that the majority of the baby droplets feature a relatively short lifetime, indicating they may potentially burn inside the flame envelope. Using droplet surface regression curves versus time, the burning rate for periods in which the atomization does not occur, and for the periods that the atomization is present are estimated. The former burning rate is shown to enhance by increasing the loading concentration and reducing the oxidation level of graphene. However, it is found that a maximum increase in the latter burning rate for both loading concentrations occurs for ethanol doped with the graphene oxide that features maximum amount of infrared radiation absorption. It is shown that relatively intense atomization suppresses the mass loss. Doping ethanol with graphene oxide and increasing the loading concentration from 0.01 to 0.1% enhances the overall burning rate, with a maximum enhancement of 8.4% pertaining to addition of reduced oxidized graphene oxide and for the loading concentration of 0.1%.