Macroscopic Determinism in Interacting Systems Using Large Deviation Theory
Brian R. La Cour, William C. Schieve

TL;DR
This paper extends large deviation theory to analyze the macroscopic deterministic behavior of large interacting systems with vector-valued observables, establishing a map that predicts system evolution with high probability as system size grows.
Contribution
It introduces a novel approach using a level-1 large deviation principle for joint observables, generalizing previous results and providing conditions for the existence of a macrostate evolution map.
Findings
Existence of a macrostate evolution map derived from a generalized dynamic free energy.
Conditions under which the macrostate map is well-defined, finite, and differentiable.
Application to a simple lattice model with an exact macroscopic solution.
Abstract
We consider the quasi-deterministic behavior of systems with a large number, , of deterministically interacting constituents. This work extends the results of a previous paper [J. Stat. Phys. 99:1225-1249 (2000)] to include vector-valued observables on interacting systems. The approach used here, however, differs markedly in that a level-1 large deviation principle (LDP) on joint observables, rather than a level-2 LDP on empirical distributions, is employed. As before, we seek a mapping on the set of (possibly vector-valued) macrostates such that, when the macrostate is given to be at time zero, the macrostate at time is with a probability approaching one as tends to infinity. We show that such a map exists and derives from a generalized dynamic free energy function, provided the latter is everywhere well defined, finite, and differentiable.…
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