Electrically detected paramagnetic resonance in Ag-paint coated DPPH

TL;DR

This paper introduces a simple, cavity-free method for detecting electron paramagnetic resonance (EPR) in DPPH using microwave current in silver paint, confirmed by impedance measurements and broadband techniques.

Contribution

The authors demonstrate a novel, cavity-free approach to EPR detection in DPPH using microwave-induced impedance changes in silver paint, expanding EPR measurement methods.

Findings

Impedance peaks at resonance field Hres increase linearly with microwave frequency.

EPR signals are confirmed with broadband coplanar waveguide measurements.

The method enables EPR detection without traditional resonators or waveguides.

Abstract

We describe a simple experimental method to detect electron paramagnetic resonance (EPR) in polycrystalline 2,2-diphenyl-1-picrylhydrazyl (DPPH) sample, the standard g-marker for EPR spectroscopy, without using a cavity resonator or a prefabricated waveguide. It is shown that microwave(MW) current injected into a layer of silver paint coated on an insulating DPPH sample is able to excite the paramagnetic resonance in DPPH. As the applied dc magnetic field H is swept, the high-frequency resistance of the Ag-paint layer, measured at room temperature with a single port impedance analyzer in the MW frequency range 1 to 2.5 GHz, exhibits a sharp peak at a critical value of the dc field (H = Hres) while the reactance exhibits a dispersion-like behavior around the same field value for a given frequency. Hres increases linearly with the frequency of MW current. We interpret the observed features in the impedance to EPR in DPPH driven by the Oersted magnetic field arising from the MW current in the Ag-paint layer. We also confirm the occurrence of EPR in DPPH independently using a coplanar waveguide-based broadband technique. This technique has the potential to investigate other EPR active inorganic and organic compounds.