Neptune's Spatial Brightness Temperature Variations from the VLA and ALMA

TL;DR

This study uses high-resolution radio observations from VLA and ALMA to map Neptune's atmospheric composition and temperature variations, revealing strong latitudinal differences and insights into its sulfur and nitrogen chemistry.

Contribution

It provides the first spatially resolved measurements of Neptune's brightness temperature and molecular abundances, employing radiative transfer modeling and MCMC methods to infer atmospheric composition.

Findings

South polar region is 5-40 K brighter than other latitudes.

H2S is more abundant than NH3, indicating strong global circulation.

Models favor H2S supersaturation over thermochemical equilibrium.

Abstract

We present spatially resolved ($0.1'' - 1.0''$) radio maps of Neptune taken from the Very Large Array and Atacama Large Submillimeter/Millimeter Array between $2015-2017$. Combined, these observations probe from just below the main methane cloud deck at $\sim 1$ bar down to the NH$_4$SH cloud at $\sim50$ bar. Prominent latitudinal variations in the brightness temperature are seen across the disk. Depending on wavelength, the south polar region is $5-40$ K brighter than the mid-latitudes and northern equatorial region. We use radiative transfer modeling coupled to Markov Chain Monte Carlo methods to retrieve H$_2$S, NH$_3$, and CH$_4$ abundance profiles across the disk, though only strong constraints can be made for H$_2$S. Below all cloud formation, the data are well fit by $53.8^{+18.9}_{-13.4}\times$ and $3.9^{+2.1}_{-3.1}\times$ protosolar enrichment in the H$_2$S and NH$_3$ abundances, respectively, assuming a dry adiabat. Models in which the radio-cold mid-latitudes and northern equatorial region are supersaturated in H$_2$S are statistically favored over models following strict thermochemical equilibrium. H$_2$S is more abundant at the equatorial region than at the poles, indicative of strong, persistent global circulation. Our results imply that Neptune's sulfur-to-nitrogen ratio exceeds unity as H$_2$S is more abundant than NH$_3$ in every retrieval. The absence of NH$_3$ above 50 bar can be explained either by partial dissolution of NH$_3$ in an ionic ocean at GPa pressures or by a planet formation scenario in which hydrated clathrates preferentially delivered sulfur rather than nitrogen onto planetesimals, or a combination of these hypotheses.