Ultra-Thin Lubricant-Infused Vertical Graphene Nanoscaffolds for High-Performance Dropwise Condensation

TL;DR

This paper introduces an ultra-thin, conductive lubricant-infused vertical graphene nanoscaffold that significantly enhances heat transfer and durability in dropwise condensation, outperforming traditional surfaces in efficiency and stability.

Contribution

The study presents a novel ultra-thin, conductive graphene-based LIS architecture that reduces thermal resistance and lubricant depletion, improving condensation performance and durability.

Findings

Doubling heat transfer performance compared to CuO LIS.

Maintains stable condensation for at least 7 hours.

Consumes 52.6% less lubricant than existing LIS.

Abstract

Lubricant-infused surfaces (LIS) are highly efficient in repelling water and constitute a very promising family of materials for condensation processes occurring in a broad range of energy applications. However, the performance of LIS in such processes is limited by the inherent thermal resistance imposed by the thickness of the lubricant and supporting surface structure, as well as by the gradual depletion of the lubricant over time. Here we present a remarkable, ultra-thin (~70 nm) and conductive LIS architecture, obtained by infusing lubricant into a vertically grown graphene nanoscaffold on copper. The ultra-thin nature of the scaffold, combined with the high in-plane thermal conductivity of graphene, drastically minimize earlier limitations, effectively doubling the heat transfer performance compared to a state-of-the-art CuO LIS surface. We show that the effect of the thermal resistance to the heat transfer performance of a LIS surface, although often overlooked, can be so detrimental that a simple nanostructured CuO surface can outperform a CuO LIS surface, despite film condensation on the former. The present vertical graphene LIS is also found to be resistant to lubricant depletion, maintaining stable dropwise condensation for at least ~7 hours with no significant change of advancing contact angle and contact angle hysteresis. The lubricant consumed by the vertical graphene LIS is 52.6% less than the existing state-of-the-art CuO LIS, making also the fabrication process more economical.