Optical cycling of AlF molecules

TL;DR

This paper demonstrates efficient optical cycling of AlF molecules, achieving high photon scattering rates and beam brightness, with potential for laser cooling and trapping in quantum applications.

Contribution

It introduces a new method for optical cycling of AlF molecules with high scattering rates using a fixed laser, and assesses loss channels for trapping.

Findings

Achieved a molecular beam brightness >10^{12} molecules/steradian/pulse.

Measured a photon scattering rate of at least 17 million per second.

Demonstrated effective deflection and acceleration of the molecular beam.

Abstract

Aluminium monofluoride (AlF) is a promising candidate for laser cooling and trapping at high densities. We show efficient production of AlF in a bright, pulsed cryogenic buffer gas beam, and demonstrate rapid optical cycling on the Q rotational lines of the $A^1\Pi \leftrightarrow X^1\Sigma^+ $ transition. We measure the brightness of the molecular beam to be $>10^{12}$ molecules per steradian per pulse in a single rotational state and present a new method to determine its velocity distribution in a single shot. The photon scattering rate of the optical cycling scheme is measured using three different methods, and is compared to theoretical predictions of the optical Bloch equations and a simplified rate equation model. Despite the large number of Zeeman sublevels (up to 216 for the Q(4) transition) involved, a high scattering rate of at least $17(2)\times 10^6$ s$^{-1}$ can be sustained using a single, fixed-frequency laser without the need to modulate the polarisation. We deflect the molecular beam using the radiation pressure force and measure an acceleration of $8.7(1.5)\times 10^5$ m/s$^2$. We demonstrate that losses from the optical cycle due to vibrational branching to $X^1\Sigma^+, v''=1$ can be addressed efficiently with a single repump laser. Further, we investigate two other loss channels, parity mixing by stray electric fields and photo-ionisation. The upper bounds for these effects are sufficiently low to allow loading into a magneto optical trap.