Loss Mechanism Analyses of Perovskite Solar Cells with an Equivalent Circuit Model

TL;DR

This paper develops an equivalent circuit model based on semiconductor physics to analyze and quantify loss mechanisms in perovskite solar cells, providing insights into efficiency limitations and guiding improvements.

Contribution

The paper introduces a reliable equivalent circuit model that accurately fits experimental data and identifies dominant recombination losses in perovskite solar cells.

Findings

Model fits experimental data with less than 2% error

Identifies dominant recombination mechanisms

Provides a clear visualization of loss contributions

Abstract

Understanding and quantifying the main loss factors affecting the power conversion efficiency of perovskite solar cells are urgently needed. In this work, based on semiconductor physics, the expressions of bulk and surface recombination currents are analytically derived. Then taking the optical loss, series and shunt resistance losses, and bulk and surface recombination losses into consideration, an equivalent circuit model is proposed to describe the current density-voltage characteristics of practical perovskite solar cells. Furthermore, by comparing to the drift-diffusion model, the pre-defined physical parameters of the drift-diffusion model well agree with the fitting parameters retrieved by the equivalent circuit model, which verifies the reliability of the proposed model. Moreover, when the circuit model is applied to analyze experimental results, the fitting outcomes show favorable consistency to the physical investigations offered by the experiments. And the relative fitting errors of the above cases are all less than 2%. Through employing the model, the dominant recombination type is clearly identified and split current density-voltage curves characterizing different loss mechanisms are offered, which intuitively reveals the physical principles of efficiency loss. Additionally, through calculating the efficiency loss ratios under the open-circuit voltage condition, quantifying the above-mentioned loss mechanisms becomes simple and compelling. Consequently, this model offers a guideline to approach the efficiency limit from a circuit-level perspective. And the model is a comprehensive simulation and analysis tool for understanding the device physics of perovskite solar cells.