Roton pair density wave and unconventional strong-coupling superconductivity in a topological kagome metal

TL;DR

This paper reports the discovery of unconventional superconductivity and a pair density wave in CsV3Sb5, a topological kagome metal, revealing complex intertwined electronic orders and providing insights into high-temperature superconductivity mechanisms.

Contribution

It demonstrates the existence of a roton pair density wave and strong-coupling superconductivity in CsV3Sb5, a novel quantum state with unique gap modulations and vortex structures.

Findings

Observation of a strong-coupling superconducting gap (~0.5 meV)

Detection of a 3Q pair density wave with spatial modulations

Identification of PDW as a primary state linked to pseudogap phenomena

Abstract

The transition-metal kagome lattice materials host frustrated, correlated, and topological quantum states of matter. Recently, a new family of vanadium-based kagome metals AV3Sb5 (A=K, Rb, and Cs) with topological band structures has been discovered. These layered compounds are nonmagnetic and undergo charge density wave transitions before developing superconductivity at low temperatures. Here we report the observation of unconventional superconductivity and pair density wave (PDW) in CsV3Sb5 using scanning tunneling microscope/spectroscopy (STM/STS) and Josephson STS. We find that CsV3Sb5 exhibits a V-shaped pairing gap {\Delta}~0.5 meV and is a strong-coupling superconductor (2{\Delta}/kBTc~5) that coexists with 4a0 unidirectional and 2a0X2a0 charge order. Remarkably, we discover a 3Q PDW accompanied by bidirectional 4a0/3 spatial modulations of the superconducting gap, coherence peak and gap-depth in the tunneling conductance. We term this novel quantum state a roton-PDW associated with an underlying vortex-antivortex lattice that can account for the observed conductance modulations. Probing the electronic states in the vortex halo in an applied magnetic field, in strong-field that suppresses superconductivity, and in zero-field above Tc reveals that the PDW is a primary state responsible for an emergent pseudogap and intertwined electronic order. Our findings show striking analogies and distinctions to the phenomenology of high-Tc cuprate superconductors, and provide groundwork for understanding the microscopic origin of correlated electronic states and superconductivity in vanadium-based kagome metals.