Two Modes of Cluster Dynamics Govern the Viscoelasticity of Colloidal Gels

TL;DR

This study reveals two distinct dynamic modes in colloidal gels that influence their viscoelastic properties, demonstrating how particle attraction strength and mixture composition can tune gel behavior.

Contribution

We identify and characterize two modes of cluster dynamics in colloidal gels and show how their interplay controls macroscopic viscoelasticity, enabling tunable gel properties.

Findings

Two dynamic modes govern gel viscoelasticity

Transition time between modes can be controlled by particle mixture

Frequency dependence of moduli can be tuned via particle attraction strengths

Abstract

Colloidal gels formed by strongly attractive particles at low particle volume fractions are composed of space-spanning networks of uniformly sized clusters. We study the thermal fluctuations of the clusters using differential dynamic microscopy by decomposing them into two modes of dynamics, and link them to the macroscopic viscoelasticity via rheometry. The first mode, dominant at early times, represents the localized, elastic fluctuations of individual clusters. The second mode, pronounced at late times, reflects the collective, viscoelastic dynamics facilitated by the connectivity of the clusters. By mixing two types of particles of distinct attraction strengths in different proportions, we control the transition time at which the collective mode starts to dominate, and hence tune the frequency dependence of the linear viscoelastic moduli of the binary gels.