Electric-field-dependent $g$ factor for the ground state of lead monofluoride, PbF
V.V. Baturo, P. M. Rupasinghe, T. J. Sears, R. J. Mawhorter, J.-U., Grabow, and A.N. Petrov
TL;DR
This paper calculates the electric-field-dependent $g$ factor and Stark splittings in lead monofluoride, showing its potential for electron EDM experiments and confirming theoretical predictions with experimental data.
Contribution
It provides the first detailed calculation of the electric-field-dependent $g$ factor for PbF's ground state and demonstrates its suitability for eEDM searches.
Findings
Good agreement between observed and calculated Zeeman shifts.
PbF hyperfine sublevels are promising for eEDM experiments.
Electric-field-dependent $g$ factor is characterized for the first time.
Abstract
The electric-field-dependent factor and the electron electric dipole moment (eEDM)-induced Stark splittings for the lowest rotational levels of PbF are calculated. Observed and calculated Zeeman shifts for PbF are found to be in very good agreement. It is shown that the PbF hyperfine sublevels provide a promising system for the eEDM search and related experiments.
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