Optical Emission from Light-like and Particle-like Excitons in Monolayer Transition Metal Dichalcogenides

TL;DR

This paper investigates the unique exciton band structures in monolayer TMDs, revealing how light-like excitons influence emission patterns and lifetimes, with implications for optoelectronic device performance.

Contribution

It introduces a comprehensive analysis of light-like excitons in TMDs, highlighting their impact on emission properties and providing first-principles calculations of exciton band structures.

Findings

Light-like excitons significantly affect emission at elevated temperatures.

Angular emission patterns are modified by the population of light-like excitons.

Experimental signatures of light-like excitons are predicted and explained.

Abstract

Several monolayer transition metal dichalcogenides (TMDs) are direct band gap semiconductors and potentially efficient emitters in light emitting devices. Photons are emitted when strongly bound excitons decay radiatively, and accurate models of such excitons are important for a full understanding of the emission. Importantly, photons are emitted in directions uniquely determined by the exciton center of mass momentum and with lifetimes determined by the exciton transition matrix element. The exciton band structures of two-dimensional hexagonal materials, including TMDs, are highly unusual with coexisting particle- and light-like bands. The latter is non-analytic with emission selection rules essentially opposite to the particle-like states, but has been ignored in analyses of TMD light emission so far. In the present work, we analyse the temperature and angular dependence of light emission from both exciton species and point out several important consequences of the unique exciton band structure. Within a first-principles Density-Functional-Theory+Bethe-Salpeter-Equation framework, we compute exciton band structures and optical matrix elements for the important TMDs MoS2, MoSe2, WS2, and WSe2. At low temperature, only the particle-like band is populated and our results agree with previous work. However, at slightly elevated temperatures, a significant population of the light-like band leads to modified angular emission patterns and lifetimes. Clear experimental fingerprints are predicted and explained by a simple four-state model incorporating spin-orbit as well as intervalley exchange coupling.