Formation of colloidal threads in geometrically varying flow-focusing channels

TL;DR

This study investigates how effective interfacial tension influences the formation of colloidal threads in flow-focusing channels, combining experiments and 3D simulations to quantify EIT's role across different geometries.

Contribution

It introduces a method to estimate effective interfacial tension in miscible fluids using experimental thread shapes and numerical modeling across various channel configurations.

Findings

Estimated EIT within 25% of optimal value.

Good agreement between simulations and experiments on thread morphology.

EIT critically affects thread detachment and flow dynamics.

Abstract

When two miscible fluids are brought into contact with each other, the concentration gradients induce stresses. These are referred to as Korteweg stresses and are analogous to interfacial tension between two immiscible fluids, thereby acting as an effective interfacial tension (EIT) in inhomogeneous miscible systems. EIT governs the formation of a viscous thread in flow-focusing of two miscible fluids. To further investigate its significance, we have studied thread formation of a colloidal dispersion focused by its own solvent. Experiments are combined with three-dimensional numerical models to systematically expand previous knowledge utilising different flow-focusing channel setups. In the reference setup, the sheath flows impinge the core flow orthogonally while in four other channel setups, the sheath flows impinge the core flow at an oblique angle that is both positive and negative with respect to the reference sheath direction. As an initial estimate of the EIT, we fit the experimentally determined thread shape in the reference setup to a master curve that depends on EIT through an effective capillary number. By numerically reproducing these experimental results, it is concluded that the estimated EIT is within 25% of the optimal EIT value that can be deduced by iteratively fitting the numerical results to the experimental measurements. Regardless of channel setups, further numerical calculations performed using the optimal EIT evaluated from the reference setup show good agreement with the experimental findings in terms of thread shapes, wetted region morphologies, and velocity flow fields. The one-to-one comparison of numerical and experimental findings unveil the crucial role of EIT on the thread detachment from the top and bottom walls of the channel, bringing useful insights to understand the physical phenomenons involved in miscible systems with a high-viscosity contrast.