Sloppy Gear Mechanism for Coupled Stochastic Transportation: from anti-equilibrium flow to infinite selectivity

TL;DR

This paper introduces a sloppy gear mechanism explaining how coupled stochastic transport in narrow channels can produce anti-equilibrium flows and selective particle transport, revealing new non-equilibrium dynamical modes.

Contribution

It presents a simple model demonstrating two transport modes and introduces a theoretical framework for particle selectivity via a passive channel mechanism.

Findings

Identification of dud and ratchet transport modes.

Discovery of anti-gradient flow driven by a sloppy gear mechanism.

Flow suppression of one particle type enabling selectivity.

Abstract

Non-equilibrium transportation of particles through a restricted space (such as porous media or narrow channels) significantly differs from free space. With a simple model of two types of particles competing to transport via a passive single-lane channel connecting two chemical baths, we find two dynamical modes of transportation -- the dud mode and the ratchet mode. At the ratchet mode, the gradient flow of one type of particle forces the other into a transient anti-equilibrium flow against its gradient. At the dud mode, the two types of particles both flow according to their gradients. This counter-intuitive non-equilibrium effect can be explained by a sloppy gear mechanism. In addition to the anti-gradient flow observed in the ratchet mode, we find that the non-equilibrium sloppy gear mechanism suppresses the flow of one particle while allowing the flow for the other. This mechanism provides a general theoretical framework to explain and design the selective transportation of particles via passive channels.