Expanded view of electron-hole recollisions in solid-state high-order harmonic generation: Full-Brillouin-zone tunneling and imperfect recollisions

TL;DR

This paper provides a comprehensive theoretical analysis of electron-hole recollisions in solid-state high-harmonic generation, revealing that harmonics often originate from extended Brillouin zone regions rather than just the minimum band gap, challenging traditional models.

Contribution

It introduces a multi-level theoretical framework to analyze HHG in solids, demonstrating the significance of extended tunneling regions and imperfect recollisions across different material structures.

Findings

Harmonics often originate from extended Brillouin zone regions.

Imperfect recollisions significantly contribute to HHG.

Different symmetry points lead to distinct harmonic profiles.

Abstract

We theoretically investigate electron-hole recollisions in high-harmonic generation (HHG) in band-gap solids irradiated by linearly and elliptically polarized drivers. We find that in many cases the emitted harmonics do not originate in electron-hole pairs created at the minimum band gap, where the tunneling probability is maximized, but rather in pairs created across an extended region of the Brillouin zone (BZ). In these situations, the analogy to gas-phase HHG in terms of the short- and long-trajectory categorizations is inadequate. Our analysis methodology comprises three complementary levels of theory: the numerical solutions to the semiconductor Bloch equations, an extended semiclassical recollision model, and a quantum wave packet approach. We apply this methodology to two general material types with representative band structures: a bulk system and a hexagonal monolayer system. In the bulk, the interband harmonics generated using elliptically-polarized drivers are found to originate not from tunneling at the minimum band gap $\Gamma$, but from regions away from it. In the monolayer system driven by linearly-polarized pulses, tunneling regions near different symmetry points in the BZ lead to distinct harmonic energies and emission profiles. We show that the imperfect recollisions, where an electron-hole pair recollide while being spatially separated, are important in both bulk and monolayer materials. The excellent agreement between our three levels of theory highlights and characterizes the complexity behind the HHG emission dynamics in solids, and expands on the notion of interband HHG as always originating in trajectories tunnelled at the minimum band gap. Our work furthers the fundamental understanding of HHG in periodic systems and will benefit the future design of experiments.