Near-unity radiative quantum efficiency of excitons in carbon nanotubes

TL;DR

This study demonstrates that bright excitons in carbon nanotubes exhibit nearly perfect radiative quantum efficiency at room temperature, achieved through cavity quantum electrodynamical effects.

Contribution

The paper introduces a method to measure and enhance the radiative quantum efficiency of carbon nanotubes using silicon photonic crystal nanobeam cavities.

Findings

Radiative quantum efficiency of bright excitons is near unity.

Cavity quantum electrodynamical effects significantly enhance exciton emission.

Room temperature operation of highly efficient carbon nanotube emitters.

Abstract

The efficiencies of photonic devices are primarily governed by radiative quantum efficiency, which is a property given by the light emitting material. Quantitative characterization for carbon nanotubes, however, has been difficult despite being a prominent material for nanoscale photonics. Here we determine the radiative quantum efficiency of bright excitons in carbon nanotubes by modifying the exciton dynamics through cavity quantum electrodynamical effects. Silicon photonic crystal nanobeam cavities are used to induce the Purcell effect on individual carbon nanotubes. Spectral and temporal behavior of the cavity enhancement is characterized by photoluminescence microscopy, and the fraction of the radiative decay process is evaluated. We find that the radiative quantum efficiency is near unity for bright excitons in carbon nanotubes at room temperature.