The TW Hya Rosetta Stone Project IV: A hydrocarbon rich disk atmosphere

TL;DR

This study uses resolved observations of C3H2 in the TW Hya disk to explore the disk's hydrocarbon chemistry and its implications for planetary atmospheres, revealing radial variations in C/O ratios that may influence planet formation.

Contribution

It provides the most extensive multi-line set of C3H2 observations in a disk, linking hydrocarbon chemistry with C/O ratio variations and planetary atmospheric compositions.

Findings

C3H2 ortho-to-para ratio is consistent with 3

Total C3H2 abundance is (7.5-10)×10^-11 per H atom

Radial variation in gas-phase C/O ratio with a sharp increase outside 30 au

Abstract

Connecting the composition of planet-forming disks with that of gas giant exoplanet atmospheres, in particular through C/O ratios, is one of the key goals of disk chemistry. Small hydrocarbons like $\rm C_2H$ and $\rm C_3H_2$ have been identified as tracers of C/O, as they form abundantly under high C/O conditions. We present resolved $\rm C_3H_2$ observations from the TW Hya Rosetta Stone Project, a program designed to map the chemistry of common molecules at $15-20$ au resolution in the TW Hya disk. Augmented by archival data, these observations comprise the most extensive multi-line set for disks of both ortho and para spin isomers spanning a wide range of energies, $E_u=29-97$ K. We find the ortho-to-para ratio of $\rm C_3H_2$ is consistent with 3 throughout extent of the emission, and the total abundance of both $\rm C_3H_2$ isomers is $(7.5-10)\times10^{-11}$ per H atom, or $1-10$% of the previously published $\rm C_2H$ abundance in the same source. We find $\rm C_3H_2$ comes from a layer near the surface that extends no deeper than $z/r=0.25$. Our observations are consistent with substantial radial variation in gas-phase C/O in TW Hya, with a sharp increase outside $\sim30$ au. Even if we are not directly tracing the midplane, if planets accrete from the surface via, e.g., meridonial flows, then such a change should be imprinted on forming planets. Perhaps interestingly, the HR 8799 planetary system also shows an increasing gradient in its giant planets' atmospheric C/O ratios. While these stars are quite different, hydrocarbon rings in disks are common, and therefore our results are consistent with the young planets of HR 8799 still bearing the imprint of their parent disk's volatile chemistry.