Hydrogenation via a low energy mechanochemical approach: the MgB$_2$ case

TL;DR

This study explores how low-energy mechanochemical milling influences solid-gas reactions, specifically synthesizing Mg(BH$_4$)$_2$ from MgB$_2$ in a hydrogen atmosphere, highlighting the importance of collision energy in the process.

Contribution

It demonstrates that wall collision energy during milling significantly affects solid-gas reactions, providing insights into low-energy mechanochemical synthesis methods.

Findings

Partial formation of Mg(BH$_4$)$_2$ observed

Collision energy impacts reaction progress

Longer milling enhances reaction effects

Abstract

This work aims at investigating the effect that the energy transferred during powder-to-wall collisions in a milling process without grinding media entails on solid-gas reactions. For this purpose, the synthesis of Mg(BH$_4$)$_2$ from MgB$_2$ in a pressurized hydrogen atmosphere was chosen as a model reaction. MgB$_2$ was milled under a broad set of milling parameters (i.e. milling times and rotation regimes) and the obtained product thoroughly characterized. By proving the partial formation of Mg(BH$_4$)$_2$, the results of this investigation indicate that the energy transferred to the powder bed by the powder particles colliding with the chamber wall during milling is not negligible, in particular when the milling process is protracted for a long period.