Significant Inverse Magnetocaloric Effect induced by Quantum Criticality

TL;DR

This paper demonstrates that quantum criticality in spin-chain materials induces a significant inverse magnetocaloric effect, offering a promising, efficient cooling mechanism for cryogenic applications.

Contribution

The study provides the first detailed many-body calculations showing inverse MCE in specific spin-1 quantum chain materials, highlighting their potential for quantum cooling technologies.

Findings

Significant inverse MCE observed near quantum critical points in TMNIN and DTN.

DTN exhibits substantial low-temperature refrigeration capacity with moderate magnetic fields.

Quantum many-body calculations accurately predict cooling performance metrics.

Abstract

The criticality-enhanced magnetocaloric effect (MCE) near a field-induced quantum critical point (QCP) in the spin systems constitutes a very promising and highly tunable alternative to conventional adiabatic demagnetization refrigeration. Strong fluctuations in the low-$T$ quantum critical regime can give rise to a large thermal entropy change and thus significant cooling effect when approaching the QCP. In this work, through efficient and accurate many-body calculations, we show there exists a significant inverse MCE(iMCE) in the spin-1 quantum chain materials(CH$_3$)$_4$NNi(NO$_2$)$_3$ (TMNIN) and NiCl$_2$-4SC(NH$_2$)$_2$ (DTN), where DTN has substantial low-$T$ refrigeration capacity while requiring only moderate magnetic fields. The iMCE characteristics, including the adiabatic temperature change $\Delta T_{\rm ad}$, isothermal entropy change $\Delta S$, differential Gr\"uneisen parameter, and the entropy change rate, are obtained with quantum many-body calculations at finite temperature. The cooling performance, i.e., the efficiency factor and hold time, of the two compounds is also discussed. Based on the many-body calculations on realistic models for the spin-chain materials, we conclude that the compound DTN constitutes a very promising and highly efficient quantum magnetic coolant with pronounced iMCE properties. We advocate that such quantum magnets can be used in cryofree refrigeration for space applications and quantum computing environments.