Moving frames and compatibility conditions for three-dimensional director fields

TL;DR

This paper uses the method of moving frames to determine the minimal local fields and compatibility conditions needed to describe three-dimensional director fields embedded in curved spaces, advancing understanding of geometric frustration.

Contribution

It introduces a set of five local fields that fully determine 3D director fields and derives six differential relations linking these fields to the space's curvature.

Findings

Five local fields suffice to describe 3D director fields.

Six differential relations connect local fields and curvature.

Classification of uniform distortion director fields in constant curvature spaces.

Abstract

The geometry and topology of the region in which a director field is embedded impose limitations on the kind of supported orientational order. These limitations manifest as compatibility conditions that relate the quantities describing the director field to the geometry of the embedding space. For example, in two dimensions (2D) the splay and bend fields suffice to determine a director uniquely (up to rigid motions) and must comply with one relation linear in the Gaussian curvature of the embedding manifold. In 3D there are additional local fields describing the director, i.e. fields available to a local observer residing within the material, and a number of distinct ways to yield geometric frustration. So far it was unknown how many such local fields are required to uniquely describe a 3D director field, nor what are the compatibility relations they must satisfy. In this work, we address these questions directly. We employ the method of moving frames to show that a director field is fully determined by five local fields. These fields are shown to be related to each other and to the curvature of the embedding space through six differential relations. As an application of our method, we characterize all uniform distortion director fields, i.e., directors for which all the local characterizing fields are constant in space, in manifolds of constant curvature. The classification of such phases has been recently provided for directors in Euclidean space, where the textures correspond to foliations of space by parallel congruent helices. For non-vanishing curvature, we show that the pure twist phase is the only solution in positively curved space, while in the hyperbolic space uniform distortion fields correspond to foliations of space by (non-necessarily parallel) congruent helices. Further analysis is expected to allow to also construct of new non-uniform director fields.