Intertwined Ferroelectricity and Topological State in Two-Dimensional Multilayer

TL;DR

This paper proposes a first-principles design paradigm for 2D ferroelectric topological insulators, demonstrating how interlayer sliding in multilayer systems can induce and control coexisting ferroelectricity and topological states for potential nanoelectronic applications.

Contribution

It introduces a novel approach to realize and manipulate ferroelectric and topological coexistence in 2D multilayers through interlayer sliding, supported by first-principles calculations.

Findings

Interlayer sliding induces ferroelectricity in 2D topological insulators.

Ferroelectric polarization flip controls topological states.

Design guidelines for ferroelectric-topological coupling in 2D materials.

Abstract

The intertwined ferroelectricity and band topology will enable the non-volatile control of the topological states, which is of importance for nanoelectrics with low energy costing and high response speed. Nonetheless, the principle to design the novel system is unclear and the feasible approach to achieve the coexistence of two parameter orders is absent. Here, we propose a general paradigm to design 2D ferroelectric topological insulators by sliding topological multilayers on the basis of first-principles calculations. Taking trilayer Bi2Te3 as a model system, we show that in the van der Waals multilayer based 2D topological insulators, the in-plane and out-of-plane ferroelectricity can be induced through a specific interlayer sliding, to enable the coexistence of ferroelectric and topological orders. The strong coupling of the order parameters renders the topological states sensitive to polarization flip, realizing non-volatile ferroelectric control of topological properties. The revealed design-guideline and ferroelectric-topological coupling not only are useful for the fundamental research of the coupled ferroelectric and topological physics in 2D lattices, but also enable novel applications in nanodevices.