Nanotribology of ionic liquids: transition to yielding response in nanometric confinement with metallic surfaces

TL;DR

This study investigates how ionic liquids confined between metallic surfaces exhibit a transition from elastic to plastic behavior at nanometric scales, significantly affecting their tribological properties and potential for self-healing lubrication.

Contribution

It reveals a confinement-induced transition to a yielding response in RTILs, linking rheological changes to tribological performance in metallic interfaces.

Findings

Abrupt rheological change below a threshold confinement

Observation of confinement-induced capillary freezing

Transition from elastic to plastic regime in shear tests

Abstract

Room Temperature Ionic Liquids (RTILs) are molten salts which exhibit uniques physical and chemical properties, commonly harnessed for lubrication and energy applications. The pure ionic nature of RTIL leads to strong electrostatic interactions among the liquid, furthermore exalted in the presence of interfaces and confinement. In this work, we use a tuning-fork based dynamic Surface Force Tribometer (TF-SFT), which allows probing both the rheological and the tribological properties of RTILs films confined between a millimetric sphere and a surface, over a wide range of confinements. When the RTIL is confined between metallic surfaces, we evidence an abrupt change of its rheological properties below a threshold confinement. This is reminiscent of a recently reported confinement induced capillary freezing, here observed with a wide contact area. In parallel, we probe the tribological response of the film under imposed nanometric shear deformation and unveil a yielding behaviour of the interfacial solid phase below this threshold confinement. This is characterized by a transition from an elastic to a plastic regime, exhibiting striking similarities with the response of glassy materials. This transition to yielding of the RTIL in metallic confinement leads overall to a reduction in friction and offers a self-healing protection of the surfaces avoiding direct contact, with obvious applications in tribology.