Recent Advances on {\pi}-Conjugated Polymers as Active Elements in High Performance Organic Field-Effect Transistors

TL;DR

This review summarizes recent progress in the design, assembly, and performance of {\pi}-conjugated polymers used as active materials in high-performance organic field-effect transistors, highlighting advances and future challenges.

Contribution

It provides a comprehensive overview of molecular design strategies, assembly techniques, and performance improvements in conjugated polymers for OFETs, emphasizing recent breakthroughs.

Findings

Some conjugated polymers achieve mobilities over 10 cm2 V-1 s-1.

Chemical modifications and alignment strategies enhance polymer performance.

Current challenges include optimizing stability and scalability.

Abstract

As high-performance organic semiconductors, {\pi}-conjugated polymers have attracted much attention due to their charming advantages including low-cost, solution processability, mechanical flexibility, and tunable optoelectronic properties. During the past several decades, the great advances have been made in polymers-based OFETs with p-type, n-type or even ambipolar characterics. Through chemical modification and alignment optimization, lots of conjugated polymers exhibited superior mobilities, and some mobilities are even larger than 10 cm2 V-1 s-1 in OFETs, which makes them very promising for the applications in organic electronic devices. This review describes the recent progress of the high performance polymers used in OFETs from the aspects of molecular design and assembly strategy. Furthermore, the current challenges and outlook in the design and development of conjugated polymers are also mentioned.