Elastic Response of Wire Frame Glasses. II. Three Dimensional Systems

TL;DR

This paper investigates the elastic behavior of three-dimensional wire frame particles in glassy suspensions, revealing how their shape influences linear and nonlinear responses, including a shear transition at a critical density.

Contribution

It introduces a geometric analysis of wire frame particles' elasticity, highlighting differences from rods and identifying a shear transition influenced by particle shape and density.

Findings

Elastic response scales as or L-shaped particles and linearly for rods.

A shear hardening to softening transition occurs at a critical density or wire frames.

Wire frames can bend due to entanglements, affecting their elastic behavior.

Abstract

We study the elastic response of rigid, wire frame particles in concentrated, glassy suspensions to a step strain by applying the simple, geometric methods developed in part I. The wire frame particles are comprised of thin, rigid rods of length $L$ and their number density, $\rho$, is such that $\rho L^3 \gg 1$. We specifically compare rigid rods to L-shapes made of two equal length rods joined at right angles. The behaviour of wire frames is found to be strikingly different from that of rods. The linear elasticity scales like $\rho^3 L^6$ for L-shaped particles, whereas it scales proportional to $\rho$ for rods and the non-linear response shows a transition from shear hardening to shear softening at a critical density $\rho_c \sim \sqrt{K / k_B T L^6}$, where $K$ is the bending modulus of the particles. For realistic particles made of double stranded DNA, this transition occurs at densities of about $\rho L^3 \sim 10$. The reason for these differences is that wire frames can be forced to bend by the entanglements with their surroundings, whereas rods always remain straight. This is found to be very important even for small strains, with most particles being bent above a critical strain $\gamma_c \sim (\rho L^3)^{-1}$.