Insights into the Electron-Electron Interaction from Quantum Monte Carlo Calculations

TL;DR

This paper uses Quantum Monte Carlo calculations to analyze the effective electron-electron interaction in the electron gas, revealing detailed spin and density dependencies, and implications for superconductivity in alkali metals.

Contribution

It provides the first comprehensive quantum Monte Carlo analysis of the full spin-dependent electron-electron interaction in the uniform electron gas.

Findings

Complete form of the electron-electron interaction obtained

Simple quadratic formulas for local field factors presented

Electron-electron interaction in lithium is attractive for certain wave vectors

Abstract

The effective electron-electron interaction in the electron gas depends on both the density and spin local field factors. Variational Diagrammatic Quantum Monte Carlo calculations of the spin local field factor are reported and used to quantitatively present the full spin-dependent, electron-electron interaction. Together with the charge local field factor from previous Diffusion Quantum Monte Carlo calculations, we obtain the complete form of the effective electron-electron interaction in the uniform three-dimensional electron gas. Very simple quadratic formulas are presented for the local field factors that quantitatively produce all of the response functions of the electron gas at metallic densities. Exchange and correlation become increasingly important at low densities. At the compressibility divergence at rs = 5.25, both the direct (screened Coulomb) term and the charge-dependent exchange term in the electron-electron interaction at q=0 are separately divergent. However, due to large cancellations, their difference is finite, well behaved, and much smaller than either term separately. As a result, the spin contribution to the electron-electron interaction becomes an important factor. The static electron-electron interaction is repulsive as a function of density but is less repulsive for electrons with parallel spins. The effect of allowing a deformable, rather than rigid, positive background is shown to be as quantitatively important as exchange and correlation. As a simple concrete example, the electron-electron interaction is calculated using the measured bulk modulus of the alkali metals with a linear phonon dispersion. The net electron-electron interaction in lithium is attractive for wave vectors $0-2k_F$, which suggests superconductivity, and is mostly repulsive for the other alkali metals.