Extended theoretical transition data in C I - IV

TL;DR

This paper provides highly accurate atomic energy levels and transition data for carbon ions C I - IV using advanced relativistic methods, improving data quality for astrophysical applications and reanalyzing solar carbon abundance.

Contribution

It introduces improved computational strategies for atomic data calculations, reducing uncertainties and enhancing the accuracy of transition probabilities for C I - IV.

Findings

Transition data uncertainties are below 9% for C I - IV.

Good agreement with experimental and theoretical data is achieved.

New data enable a refined reanalysis of solar carbon abundance.

Abstract

Accurate atomic data are essential for opacity calculations and for abundance analyses of the Sun and other stars. The aim of this work is to provide accurate and extensive results of energy levels and transition data for C I - IV. The Multiconfiguration Dirac-Hartree-Fock and relativistic configuration interaction methods were used in the present work. To improve the quality of the wave functions and reduce the relative differences between length and velocity forms for transition data involving high Rydberg states, alternative computational strategies were employed by imposing restrictions on the electron substitutions when constructing the orbital basis for each atom and ion. Transition data, e.g., weighted oscillator strengths and transition probabilities, are given for radiative electric dipole (E1) transitions involving levels up to 1s$^2$2s$^2$2p6s for C I, up to 1s$^2$2s$^2$7f for C II, up to 1s$^2$2s7f for C III, and up to 1s$^2$8g for CIV. Using the difference between the transition rates in length and velocity gauges as an internal validation, the average uncertainties of all presented E1 transitions are estimated to be 8.05%, 7.20%, 1.77%, and 0.28%, respectively, for C I - IV. Extensive comparisons with available experimental and theoretical results are performed and good agreement is observed for most of the transitions. In addition, the C I data were employed in a reanalysis of the solar carbon abundance. The new transition data give a line-by-line dispersion similar to the one obtained when using transition data that are typically used in stellar spectroscopic applications today.