Facile and Fast Transformation of Non-Luminescent to Highly Luminescent MOFs: Acetone Sensing for Diabetes Diagnosis and Lead Capture from Polluted Water

TL;DR

This study demonstrates a rapid, post-synthetic transformation of a non-luminescent MOF into a highly luminescent one for acetone sensing and lead capture, offering new pathways for environmental and medical applications.

Contribution

It introduces a simple immersion method to convert non-luminescent MOFs into luminescent frameworks using uncoordinated oxygen atoms, enabling dual applications in sensing and pollutant removal.

Findings

Transformed MOFs exhibit high luminescence and selectivity for acetone detection.

The method is extendable to other metals like lead for environmental remediation.

Polymer membranes with transformed MOFs effectively capture lead ions from water.

Abstract

Metal-organic frameworks (MOFs) stand as one of the most promising materials for the development of advanced technologies owing to their unique combination of properties. The conventional synthesis of MOFs involves a direct reaction of the organic linkers and metal salts, however, their post-synthetic modification is a sophisticated route to produce new materials or to confer novel properties that cannot be attained through traditional methods. This work describes the post-synthetic MOF-to-MOF transformation of a non-luminescent MOF (Zn-based OX-1) into a highly luminescent framework (Ag-based OX-2) by a simple immersion of the former in a silver salt solution. The conversion mechanism exploits the uncoordinated oxygen atoms of terephthalate linkers found in OX-1, instead of the unsaturated metal sites commonly employed, making the reaction much faster. The materials derived from the OX-1 to OX-2 transformation are highly luminescent and exhibit a selective response to acetone, turning them into a promising candidate for manufacturing fluorometric sensors for the diagnosis and monitoring of diabetes mellitus. Our methodology can be extended to other metals such as lead (Pb). The fabrication of a polymer mixed-matrix membrane containing OX-1 is used as a proof-of-concept for capturing Pb ions (as pollutants) from water. This research instigates the exploration of alternative methodologies to confer MOFs with special aptitudes for photochemical sensing or for environmental applications such as water purification.