Understanding interlaminar toughening of unidirectional CFRP laminates with carbon nanotube veils

TL;DR

This study investigates how nanostructured carbon nanotube veils improve the interlaminar toughness of unidirectional CFRP composites, revealing the effects of infiltration and microstructure on failure mechanisms and mechanical performance.

Contribution

It provides new insights into the failure mechanisms and microstructural effects of CNT veils in aerospace-grade composites, highlighting the importance of infiltration and bridging for reinforcement.

Findings

Mode II interlaminar fracture toughness increased by 88%.

Mode I fracture toughness decreased by 21%.

Interlayer infiltration influences failure modes and reinforcement effectiveness.

Abstract

The introduction of nanostructured interlayers is one of the most promising strategies for interlaminar reinforcement in structural composites. In this work, we study the failure mechanism and interlayer microstructure of aerospace-grade structural composites reinforced with thin veils of carbon nanotube produced using an industrialised spinning process. Samples of unidirectional carbon fibre/epoxy matrix composites interleaved with different composition CNT veils were prepared using hot press method and tested for interlaminar fracture toughness (IFT), measured in Mode-I (opening) and Mode-II (in-plane shear), and for interlaminar shear strength (ILSS), evaluated by the short beam shear (SBS) test. The crack propagation mode could be directly determined through fractography analysis by electron microscopy and resin/CNT spatial discrimination by Raman spectroscopy, showing a clear correlation between interlaminar reinforcement and the balance between cohesive/adhesive failure mode at the interlayer region. Composites with full resin infiltration of the CNT veils give a large increase of Mode II IFT (88%) to 1500 J/m2 and a slight enhancement of apparent interlaminar shear strength (6.5%), but a decrease of Mode I IFT (-21%). The results help establish the role of interlayer infiltration, interlaminar crossings and formation of a carbon fibre bridgings, for interlaminar reinforcement with interleaves.