d0 Ferromagnetism in Ag-doped Monoclinic ZrO2 Compounds

TL;DR

This study demonstrates that doping monoclinic ZrO2 with silver induces ferromagnetism, with Curie temperature increasing with Ag concentration, suggesting potential for d0 ferromagnetic applications.

Contribution

First comprehensive analysis of Ag-doped ZrO2 showing induced ferromagnetism and detailed magnetic property evolution with doping levels.

Findings

Ag doping induces ferromagnetism in ZrO2.

Curie temperature increases with Ag concentration.

High-temperature sintering reduces ferromagnetism.

Abstract

Recently d0 or intrinsic ferromagnetism was believed to provide an alternative pathway to transition metal induced ferromagnetism in oxide. In pursuit of augmenting the area of d0 ferromagnetism; we have undertaken to study the crystal structure and magnetic properties of Ag-doped ZrO2 compounds. Polycrystalline samples of Zr1-xAgxO2 (with x=0, 0.02, 0.04, 0.06 and 0.08) were prepared by solid-state reaction route. All the prepared compounds are found to crystallize in monoclinic symmetry of ZrO2. In our study, pure ZrO2 compound exhibits paramagnetic behavior. However, the Ag-doped ZrO2 compounds exhibit ferromagnetic to paramagnetic transition. The Curie temperature was found to increase from 28.7 K for x=0.02 to 173.2 K for x= 0.08 doped ZrO2. Thus, the introduction of Ag in ZrO2 induces ferromagnetism with a large ThetaC. The measurements of hysteresis curves indicate that Ag doped ZrO2 compounds exhibit hysteresis loops with a coercivity of around 1350 Oe. Moreover, increase in Ag concentration resulted increase in the value of saturation magnetization (MS); the maximum value of MS was recorded as 0.01 {\mu}B/Ag ion for x= 0.06 sample. The sintering of sample at high temperature (13500C) diminishes the ferromagnetism and it leads to paramagnetic behaviour.