Variable refractory lithophile element compositions of planetary building blocks: insights from components of enstatite chondrites

TL;DR

This study reveals that refractory lithophile element ratios vary in enstatite chondrites, indicating complex formation processes and challenging the assumption of constant RLE ratios in planetary building blocks.

Contribution

It demonstrates that RLE ratios are fractionated in chondrules of enstatite chondrites, providing new insights into planetary formation and the chemical diversity of early solar system materials.

Findings

RLE ratios vary in enstatite chondrite chondrules.

Bulk EC have solar-like RLE ratios, indicating minimal physical sorting.

Implications for Earth's accretion and planetary composition models.

Abstract

Chondrites are sediments of materials left over from the earliest stage of the solar system history. Based on their undifferentiated nature and less fractionated chemical compositions, chondrites are widely considered to represent the unprocessed building blocks of the terrestrial planets and their embryos. Models of chemical composition of the terrestrial planets generally find chondritic relative abundances of refractory lithophile elements (RLE) in the bulk bodies ("constant RLE ratio rule"), based on limited variations of RLE ratios among chondritic meteorites and the solar photosphere. Here, we show that ratios of RLE, such as Nb/Ta, Zr/Hf, Sm/Nd and Al/Ti, are fractionated from the solar value in chondrules from enstatite chondrites (EC). The fractionated RLE ratios of individual EC chondrules document different chalcophile affinities of RLE under highly reducing environments and a separation of RLE-bearing sulfides from silicates before and/or during chondrule formation. In contrast, the bulk EC have solar-like RLE ratios, indicating that a physical sorting of silicates and sulfides was negligible before and during the accretion of EC parent bodies. Likewise, if the Earth's accretion were dominated by EC-like materials, as supported by multiple isotope systematics, the physical sorting of silicates and sulfides in the accretionary disk should not have occurred among the Earth's building blocks. Alternatively, the Earth's precursors might have been high-temperature nebular materials that condensed before the RLE fractionation due to precipitation of the RLE-bearing sulfides...Highly reduced planets that have experienced selective removal or accretion of silicates or metal/sulfide phases, such as Mercury, might have fractionated, non-solar bulk RLE ratios.