Controlling Photoluminescence Spectra of hBN Color Centers by Selective Phonon-Assisted Excitation: A Theoretical Proposal

TL;DR

This paper proposes a theoretical method to control the photoluminescence spectra of hBN color centers by exploiting phonon-assisted excitation, enabling manipulation of phonon modes and quantum beats for quantum information applications.

Contribution

It introduces a theoretical approach to selectively excite phonon modes in hBN color centers, revealing control over phonon dynamics and PL signals.

Findings

Phonon decay dynamics influence time-dependent PL signals.

Tailored optical excitation can generate phonon quantum beats.

Spectral separation allows selective phonon mode control.

Abstract

Color centers in hexagonal boron nitride (hBN) show stable single photon emission even at room temperature, making these systems a promising candidate for quantum information applications. Besides this remarkable property, also their interaction with longitudinal optical (LO) phonons is quite unique because they lead to dominant phonon sidebands (PSBs), well separated from the zero phonon line (ZPL). In this work we utilize this clear spectral separation to theoretically investigate the influence of phonon decay dynamics on time-dependent photoluminescence (PL) signals. Our simulations show, that by using tailored optical excitation schemes it is possible to create a superposition between the two LO modes, leading to a phonon quantum beat that manifests in the time-dependent PL signal.