Magnetic anisotropy of individual maghemite mesocrystals

TL;DR

This study uses sensitive magnetometry to measure the magnetic anisotropy of individual maghemite mesocrystals, revealing cubic anisotropy due to nanoparticle crystalline properties and alignment within ordered superstructures.

Contribution

It demonstrates the first direct measurement of magnetic anisotropy in individual mesocrystals, combining self-assembly with high-resolution magnetometry.

Findings

Unambiguous cubic anisotropy observed in individual mesocrystals

Anisotropy arises from nanoparticle crystalline properties and alignment

Method enables study of magnetic properties of nanoscale particles

Abstract

Interest in creating magnetic metamaterials has led to methods for growing superstructures of magnetic nanoparticles. Mesoscopic crystals of maghemite ($\gamma\text{-Fe}_2\text{O}_3$) nanoparticles can be arranged into highly ordered body-centered tetragonal lattices of up to a few micrometers. Although measurements on disordered ensembles have been carried out, determining the magnetic properties of individual mesoscopic crystals is challenging due to their small total magnetic moment. Here, we overcome these challenges by utilizing sensitive dynamic cantilever magnetometry to study individual micrometer-sized $\gamma\text{-Fe}_2\text{O}_3$ mesocrystals. These measurements reveal an unambiguous cubic anisotropy, resulting from the crystalline anisotropy of the constituent maghemite nanoparticles and their alignment within the mesoscopic lattice. The signatures of anisotropy and its orgins come to light because we combine the self-assembly of highly ordered mesocrystals with the ability to resolve their individual magnetism. This combination is promising for future studies of the magnetic anisotropy of other nanoparticles, which are too small to investigate individually.