Reduction of g-factor due to Rashba effect in graphene

TL;DR

This paper investigates how the Rashba effect, caused by surface work function, contributes to the reduction of the g-factor in graphene, complementing previous explanations based on diamagnetism.

Contribution

It introduces a simple model incorporating the Rashba and Zeeman effects to explain the g-factor reduction in graphene, aligning well with experimental observations.

Findings

Rashba effect significantly reduces the g-factor in graphene.

The model's results closely match experimental data.

Rashba effect accounts for the remaining g-factor reduction beyond diamagnetism.

Abstract

Graphene is a highly promising material in the field of spin electronics. Recent experiments on electron spin resonance have observed a reduction in the g-factor of graphene. In our previous paper [J. Phys. Soc. Jpn. 88, 094707 (2019)], we demonstrated that one of sources for this reduction is the diamagnetic property of graphene. However, the diamagnetic property by itself does not fully account for the magnitude of the reduction observed in the experiments. In this paper, we focus on the Rashba effect, which is caused by the work function existing near the surface of graphene. The Rashba effect tilts the spin magnetic moment to the in-plane direction of the graphene sheet, potentially reducing the g-factor. We evaluate this reduction using a simple model system incorporating the Rashba and spin Zeeman effects. We then demonstrate that the resultant g-factor is in close agreement with that observed in the prior experiments, indicating that the Rashba effect is able to account for the remaining reduction in the g-factor of graphene.