Electron-stimulated desorption from molecular ices in the sub-keV regime

TL;DR

This study investigates electron-stimulated desorption from molecular ices at sub-keV energies, revealing new insights into energy deposition and species diffusion relevant to vacuum systems and astrochemistry.

Contribution

It introduces the concept of desorption-relevant depth to explain ESD yield variations and compares different molecular ices in the sub-keV regime.

Findings

ESD yields depend on electron energy in the 150-2000 eV range.

Desorption-relevant depth characterizes the transition in energy deposition regimes.

Differences in species diffusion are revealed in crystalline versus porous amorphous CO$_2$ ices.

Abstract

Electron-stimulated desorption (ESD) of cryosorbed molecules on surfaces is a process of relevance to fields as varied as vacuum dynamics in accelerators and astrochemistry. While desorption from such molecular systems induced by keV electrons and fast ions has been extensively studied, the sub-keV electron regime is comparatively little known. We measured and quantified electron-stimulated desorption from molecular ice systems (layers of N$_2$, CO, CO$_2$, Ar and H$_2$O/D$_2$O condensed at cryogenic temperatures) in the 150-2000 eV electron energy range. In this regime stopping power is no longer sufficient to explain the electron energy dependence of ESD yields. We introduce the notion of desorption-relevant depth, which characterizes the transition between two energy deposition regimes near the surface. We then apply this notion to the different systems, showing how ESD in the sub-keV regime can for example reveal the differences in species diffusion in crystalline and porous amorphous CO$_2$ ices.