Single-mode lasing from a single 7 nm thick monolayer of colloidal quantum wells in a monolithic microcavity

TL;DR

This paper reports the first monolithically-fabricated VCSELs using a 7 nm thick colloidal quantum well film, demonstrating single-mode lasing with potential for electrically-driven colloidal lasers.

Contribution

It introduces a novel hybrid CQW-VCSEL design with ultra-thin gain media and demonstrates single-mode lasing from a monolayer of colloidal quantum wells.

Findings

Achieved single-mode lasing from a 7 nm thick CQW film.

Demonstrated mode tuning with dielectric layer integration.

Overcame conductivity issues in ultra-thin colloidal films.

Abstract

In this work, we report the first account of monolithically-fabricated vertical cavity surface emitting lasers (VCSELs) of densely-packed, orientation-controlled, atomically flat colloidal quantum wells (CQWs) using a self-assembly method and demonstrate single-mode lasing from a record thin colloidal gain medium with a film thickness of 7 nm under femtosecond optical excitation. We used specially engineered CQWs to demonstrate these hybrid CQW-VCSELs consisting of only a few layers to a single monolayer of CQWs and achieved the lasing from these thin gain media by thoroughly modeling and implementing a vertical cavity consisting of distributed Bragg reflectors with an additional dielectric layer for mode tuning. Accurate spectral and spatial alignment of the cavity mode with the CQW films was secured with the help of full electromagnetic computations. While overcoming the long-pending problem of limited electrical conductivity in thicker colloidal films, such ultra-thin colloidal gain media can help enabling fully electrically-driven colloidal lasers.