Synthesis of narrow SnTe nanowires using alloy nanoparticles

TL;DR

This paper presents a simple method to synthesize narrow SnTe nanowires using alloy nanoparticles, enabling the study of 1D topological and ferroelectric phenomena with improved control over nanowire dimensions.

Contribution

The study introduces a novel alloy nanoparticle catalyst approach to produce significantly narrower SnTe nanowires with high yield, facilitating advanced electronic property investigations.

Findings

Nanowire diameter reduced to 85 nm using alloy catalysts

Ferroelectric transition temperature varies with nanowire diameter

In situ TEM reveals structural transition related to ferroelectricity

Abstract

Topological crystalline insulator tin telluride (SnTe) provides a rich playground to examine interactions of correlated electronic states, such as ferroelectricity, topological surface states, and superconductivity. Making SnTe into nanowires further induces novel electronic states due to one-dimensional (1D) confinement effects. Thus, for transport measurements, SnTe nanowires must be made narrow in their diameters to ensure the 1D confinement and phase coherence of the topological surface electrons. This study reports a facile growth method to produce narrow SnTe nanowires with a high yield using alloy nanoparticles as growth catalysts. The average diameter of the SnTe nanowires grown using the alloy nanoparticles is 85 nm, nearly a factor of three reduction from the previous average diameter of 240 nm using gold nanoparticles as growth catalysts. Transport measurements reveal the effect of the nanowire diameter on the residual resistance ratio and magnetoresistance. Particularly, the ferroelectric transition temperature for SnTe is observed to change systematically with the nanowire diameter. In situ cryogenic cooling of narrow SnTe nanowires in a transmission electron microscope directly reveals the cubic to rhombohedral structural transition, which is associated with the ferroelectric transition. Thus, these narrow SnTe nanowires represent a model system to study electronic states arising from the 1D confinement, such as 1D topological superconductivity as well as a potential multi-band superconductivity.