Understanding the non-collinear antiferromagnetic IrMn$_3$ surfaces and their exchange-biased heterostructures from first principles

TL;DR

This study uses first-principles calculations to analyze the stability, magnetic properties, and exchange-bias effects of IrMn$_3$/Fe heterostructures, revealing how atomic configurations influence magnetic coupling and exchange bias.

Contribution

It provides a detailed atomic-level understanding of the magnetic coupling and exchange bias in IrMn$_3$/Fe heterostructures, including the relationship between Mn-Fe interactions and exchange bias strength.

Findings

Identified two stable surface terminations consistent with experimental data.

Discovered the correlation between Mn-Fe interactions and exchange bias intensity.

Described the atom-by-atom magnetic coupling at the interface.

Abstract

We provide a complete and systematic first-principles study of the thermodynamic stability, structural parameters, and magnetic properties of the T1 non-collinear antiferromagnetic L1$_2$-IrMn$_3$ surface and L1$_2$-IrMn$_3$/Fe heterostructure. Furthermore, we investigate the exchange-bias effect in the heterostructure and describe its previously unknown complex magnetic coupling at the interface. We consider four atomic configurations and four magnetic arrangements, finding two stable terminations for the surface and for the heterostructure, which are in good agreement with experimental HR-TEM data. Using a comparative approach to analyze the exchange-bias properties of the heterostructure, we discover that the number of Mn-Fe interactions is related to the exchange bias intensity. This finding could lead to novel exchange-bias tailoring methods by controlling the termination of the layers. Finally, we are able to accurately describe the interface magnetic coupling atom-by-atom, and we find a relationship between the antiferromagnetic order at the interface and the stability of the heterostructure. Our analysis provides a possible mechanism for the appearance of exchange bias in non-collinear/collinear heterostructures, and it is in good agreement with experimental hysteresis measurements of the IrMn$_3$/Fe system.