Ferrofluidic aqueous two-phase system with ultralow interfacial tension, instabilities and pattern formation

TL;DR

This paper introduces a novel aqueous ferrofluid system with ultralow interfacial tension, enabling the study of magnetic instabilities and pattern formation at microscale levels, which was previously challenging due to high interfacial energies.

Contribution

The authors develop a fully aqueous ferrofluid system using polymer phase separation, achieving ultralow interfacial tension and enabling miniaturized magnetic pattern formation.

Findings

Demonstrated normal-field instability in the aqueous ferrofluid system.

Achieved pattern miniaturization from 10 mm to 200 μm.

Provided a method to evaluate extremely small interfacial tensions.

Abstract

Ferrofluids are strongly magnetic fluids consisting of magnetic nanoparticles dispersed in a carrier fluid. Besides their technological applications, they have a tendency to form beautiful and intriguing patterns when subjected to external static and dynamic magnetic fields. Most of the patterns occur in systems consisting of two fluids: one ferrofluidic and one non-magnetic (oil, air, etc.), wherein the fluid-fluid interface deforms as a response to magnetic fields. Usually, the fluids are completely immiscible and so the interfacial energy in this systems is very large. Here we show that it is possible to design a fully aqueous ferrofluid system by using phase separation of incompatible polymers. This continuous aqueous system allows an ultralow interfacial tension (down to 1 $\mu$N/m) and nearly vanishing pinning at three phase contact lines. We demonstrate the normal-field instability with the system and focus on the miniaturization of the pattern length from the typical $\sim$10 mm size down to $\sim$200 $\mu$m. The normal-field instability is characterized in glass capillaries of thickness comparable to the pattern length. This system paves way towards interesting physics such as the interaction between magnetic instabilities and thermal capillary waves and offers a way to evaluate extremely small interfacial tensions.