Study of SiGeSn/GeSn single quantum well towards high-performance all-group-IV optoelectronics
Grey Abernathy, Yiyin Zhou, Solomon Ojo, Bader Alharthi, Perry C., Grant, Wei Du, Joe Margetis, John Tolle, Andrian Kuchuk, Baohua Li, and, Shui-Qing Yu

TL;DR
This paper investigates the optical properties of a SiGeSn/GeSn single quantum well to inform high-performance all-group-IV optoelectronic device development, focusing on band structure and photoluminescence analysis.
Contribution
It provides a detailed analysis of the band alignment and optical transitions in SiGeSn/GeSn SQWs, aiding future quantum well design for optoelectronic applications.
Findings
The SQW has a direct bandgap with a 50 meV L-{ extGamma} valley separation.
Barrier heights for electrons and holes exceed 80 meV.
PL spectra analysis reveals multiple optical transitions.
Abstract
The recent progress on (Si)GeSn optoelectronic devices holds a great promising for photonic integration on the Si substrate. In parallel to the development of bulk devices, the (Si)GeSn based quantum wells (QWs) have been investigated aiming to improve the device performance. While the multiple QW structure is preferred for the device application, the single quantum well (SQW) is more suitable for optical property study. In this work, a comprehensive study of a SiGeSn/GeSn SQW was conducted. The calculated band diagram provided the band alignment and energies of possible transitions. The SQW features the direct bandgap well with L-{\Gamma} valley energy separation of 50 meV, and the barrier heights for both electron and hole are greater than 80 meV. Using two continuous-wave and two pulsed pumping lasers, the analysis of PL spectra allows for identifying different transitions and for…
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