The recombination region in lean steady premixed H$_2$ flames

TL;DR

This paper investigates the structure and kinetics of the recombination region in lean premixed H$_2$ flames, revealing it as a second order, isothermal zone dominated by H$_2$ distribution and HO$_2$ kinetics, with implications for flame decay dynamics.

Contribution

It provides a detailed analysis of the recombination region in H$_2$ flames, highlighting the quenching of shuffle reactions and its impact on flame structure and decay mechanisms.

Findings

Recombination region is isothermal and dominated by H$_2$ distribution.

Decay to equilibrium is controlled by HO$_2$ kinetics and convective transport.

The region's length scale is large enough to neglect diffusive transport.

Abstract

H$_2$ premixed flames are well known for a long, trailing region where the unburnt H$_2$ and the super-equilibrium concentrations of radicals left past the fuel consumption layer gradually decay to thermodynamic equilibrium. This recombination region, it's argued here, is a second order effect induced by the premature quenching of the shuffle reactions, which inhibits the decay to equilibrium in the first approximation. Its structure and kinetics are studied in detail to capture the small but finite reaction rates accounting for its characteristic length scale, which is large enough to render the diffusive transport negligible, hence deactivating the upstream feedback link with the main flame structure. It is isothermal and can be described, in moderately lean flames, by just the distribution of H$_2$ as the sole degree of freedom, a drastic reduction consequence of the strongly constrained evolution imposed by the almost exactly quenched shuffle reactions. The rate of decay to equilibrium of H$_2$ and radicals is thus dictated by the balance between the convective transport and chemical sinks controlled by the HO$_2$ kinetics, which becomes dominant after the shuffle reactions quench. Essentially, it is a two-step mechanism with the first, rate-limiting step converting O$_2$ into HO$_2$, whereas the second one, comprising multiple fast, parallel pathways, depletes radicals as HO$_2$ is converted into O$_2$ and H$_2$O. Generalizations to very lean and nearly stoichiometric flames, when the one degree of freedom model is not applicable, as well as the effect of heat losses are also briefly discussed.