Isotropic-Nematic Phase Transition and Liquid Crystal Droplets

TL;DR

This paper rigorously analyzes the isotropic-nematic phase transition in liquid crystal droplets using the Ericksen model, deriving a sharp interface limit that describes droplet shape and surface anchoring conditions based on material parameters.

Contribution

It establishes a $ ext{Gamma}$-convergence theorem for the phase transition, connecting microscopic parameters to macroscopic droplet shape and boundary conditions.

Findings

Derives a sharp interface limit for the phase transition.

Provides geometric description of droplet shape.

Predicts natural emergence of boundary anchoring conditions.

Abstract

Liquid crystal droplets are of great interest from physics and applications. Rigorous mathematical analysis is challenging as the problem involves harmonic maps (and in general the Oseen-Frank model), free interfaces and topological defects which could be either inside the droplet or on its surface along with some intriguing boundary anchoring conditions for the orientation configurations. In this paper, through a study of the phase transition between the isotropic and nematic states of liquid crystal based on the Ericksen model, we can show, when the size of droplet is much larger in comparison with the ratio of the Frank constants to the surface tension, a $\Gamma$-convergence theorem for minimizers. This $\Gamma$-limit is in fact the sharp interface limit for the phase transition between the isotropic and nematic regions when the small parameter $\varepsilon$, corresponding to the transition layer width, goes to zero. This limiting process not only provides a geometric description of the shape of the droplet as one would expect, and surprisingly it also gives the anchoring conditions for the orientations of liquid crystals on the surface of the droplet depending on material constants. In particular, homeotropic, tangential, and even free boundary conditions as assumed in earlier phenomenological modelings arise naturally provided that the surface tension, Frank and Ericksen constants are in suitable ranges.