Dynamics of the sub-ambient gelation and shearing of solutions of P3HT incorporated with a non-fullerene acceptor o-IDTBR towards active layer formation in bulk heterojunction organic solar cells

TL;DR

This study investigates the gelation behavior of P3HT with a non-fullerene acceptor o-IDTBR under sub-ambient conditions, revealing how shear and composition influence gel stability and implications for organic solar cell processing.

Contribution

It provides new insights into the gelation dynamics of P3HT/o-IDTBR blends under sub-ambient conditions, informing scalable processing methods for organic solar cells.

Findings

Gel strength depends on concentration, solvent, and shear conditions.

Gels are stable under small oscillations but break down under steady shear.

Shearing during processing can alter gel structure and device performance.

Abstract

Organic solar cells (OSCs) containing an active layer consisting of a nanostructured blend of a conjugated polymer like poly(3-hexylthiophene) (P3HT) and an electron acceptor molecule have the potential of competing against silicon-based photovoltaic panels. However, this potential is unfulfilled primarily due to interrelated production and stability issues. The generally employed spin coating process for fabricating organic solar cells cannot be scaled up. Recently, He et al., have reported that the gelation of P3HT with [6,6]-phenyl-C61-butyric acid methyl ester (PC60BM) under sub-ambient conditions can provide a continuous extrusion/coating based route to the processing of organic solar cells and that increases in power conversion efficiencies (PCEs) of the P3HT/PC60BM active layer are possible under certain shearing and thermal histories of the P3HT/PC60BM gels. Here oscillatory and steady torsional flows were used to investigate the gel formation dynamics of P3HT with a recently proposed non-fullerene o-IDTBR under sub-ambient conditions. The gel strengths defined on the basis of linear viscoelastic material functions as determined via small-amplitude oscillatory shear were observed to be functions of the P3HT and o-IDTBR concentrations, the solvent used and the shearing conditions. Overall, the gels which formed upon quenching to sub-zero temperatures were found to be stable during small-amplitude oscillatory shear (linear viscoelastic range) but broke down even at the relatively low shear rates associated with steady torsional flows, suggesting that the shearing conditions used during the processing of gels of P3HT with small molecule acceptor blends can alter the gel structure and possibly affect the resulting active layer performance.