Mass transfer from a fluid flowing through a porous media

TL;DR

This paper develops an analytical mathematical model for mass transfer in a fluid flowing through porous media, applicable to contaminant removal, and validates it with experimental data, offering a tool for process optimization.

Contribution

The paper introduces a simplified analytical model for mass transfer in porous media, improving upon existing models and enabling easier process optimization.

Findings

Model accurately predicts breakthrough curves

Analytical solution simplifies process optimization

Better agreement with experimental data than previous models

Abstract

A mathematical model is developed for the process of mass transfer from a fluid flowing through a packed column. Mass loss, whether by absorption or adsorption, may be significant. This is appropriate for example when removing contaminants from flue gases. With small mass loss the model reduces to a simpler form which is appropriate to describe the removal of contaminants/pollutants from liquids. A case study is carried out for the removal of CO2 from a gas mixture passing over activated carbon. Using the experimental parameter values it is shown, via non-dimensionalisation, that certain terms may be neglected from the governing equations, resulting in a form which may be solved analytically using a travelling wave substitution. From this all important quantities throughout the column may be described; concentration of gaseous materials, amount of material available for mass transfer, fluid velocity and pressure. Results are verified by comparison with experimental data for the breakthrough curve (the amount of carbon measured at the column outlet). The advantage of the analytical expression over a purely numerical solution is that it can easily be used to optimise the process. In the final section we demonstrate how the model may be further reduced when small amounts of contaminant are removed. The model is shown to exhibit better agreement than established models when compared to experimental data for the removal of amoxicillin and congo red dye from water.