Spin state crossover in Co3BO5
N.V. Kazak, M.S. Platunov, Yu.V. Knyazev, M.S. Molokeev, M.V. Gorev,, S.G. Ovchinnikov, Z.V. Pchelkina, V.V. Gapontsev, S.V. Streltsov, J., Bartolom\'e, A. Arauzo, V.V. Yumashev, S.Yu. Gavrilkin, F. Wilhelm, A., Rogalev
TL;DR
This study investigates the spin state crossover in Co3BO5 through experimental techniques like XMCD, magnetic susceptibility, and heat capacity, complemented by GGA+U calculations, revealing detailed magnetic and structural properties.
Contribution
It provides a comprehensive analysis of the spin state crossover in Co3BO5 combining experimental and theoretical methods.
Findings
Identification of spin state crossover in Co3BO5.
Detailed crystal structure determination at various temperatures.
Correlation between magnetic properties and electronic structure.
Abstract
The magnetic contribution of the Co3+ ions in Co3BO5 has been investigated using the Co (K-edge) XMCD, dc magnetic susceptibility, and heat capacity measurements. The crystal structure of Co3BO5 single crystal has been solved in detail at the T range 296-703 K. The results have been supplemented by the GGA+U calculations.
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