Thermal conductivity of PbTe-CoSb3 bulk polycrystalline composite: the role of microstructure and interface thermal resistance

TL;DR

This study investigates how microstructure and interface thermal resistance influence the thermal conductivity of PbTe-CoSb3 composites, highlighting the importance of particle size and interface properties in thermoelectric material design.

Contribution

It provides a systematic experimental and theoretical analysis of the effects of particle size and interface resistance on phonon thermal conductivity in PbTe-CoSb3 composites.

Findings

Smaller CoSb3 particles (<230nm) reduce thermal conductivity.

Interface thermal resistance correlates with particle size and acoustic impedance.

Controlling microstructure can tailor thermoelectric properties.

Abstract

Systematic experimental and theoretical research on the role of microstructure and interface thermal resistance on the thermal conductivity of the PbTe-CoSb3 bulk polycrystalline composite is presented. In particular, the correlation between the particle size of the dispersed phase and interface thermal resistance (R_{int}) on the phonon thermal conductivity (\kappa_{ph}) is discussed. With this aim, a series of PbTe-CoSb_3 polycrystalline composite materials with the different particle sizes of CoSb_3 was prepared. The structural (XRD) and microstructural analysis (SEM/EDXS) confirmed assumed chemical and phase compositions. The acoustic impedance difference (\Delta Z) was determined from measured sound velocities in PbTe and CoSb_3 phases. The interface thermal resistance (R_{int}) was calculated using the Debye model and agrees with the experimental R_{int}. It is shown that the \kappa_{ph} of the composite may be reduced when the particle size of the dispersed phase (CoSb_3) is smaller than the critical value of ~230nm. This relationship was concluded to be crucial for controlling the heat transport phenomena in composite thermoelectric materials. The selection of the components with different elastic properties (acoustic impedance) and particle size smaller than the Kapitza radius leads to a new direction in the engineering of composite TE materials with designed thermal properties