Large-Scale and Robust Multifunctional Vertically-Aligned MoS$_2$ Photo-Memristors

TL;DR

This paper presents a scalable method to produce large-area vertically aligned MoS$_2$ memristors that are low-voltage, thermally stable, and photo-responsive, suitable for advanced non-volatile memory and neuromorphic computing.

Contribution

It introduces a simple, robust growth technique for large-scale VA-MoS$_2$ films and demonstrates their multifunctional memristive properties with optical responsiveness.

Findings

Low set-ON voltages (<0.5V)

Retention times over 20,000 seconds

Thermal stability up to 350°C

Abstract

Memristive devices have drawn considerable research attention due to their potential applications in non-volatile memory and neuromorphic computing. The combination of resistive switching devices with light-responsive materials is considered a novel way to integrate optical information with electrical circuitry. On the other hand, 2D materials have attracted substantial consideration thank to their unique crystal structure, as reflected in their chemical and physical properties. Although not the major focus, van der Waals solids were proven to be potential candidates in memristive devices. In this scheme, the majority of the resistive switching devices were implemented on planar flakes, obtained by mechanical exfoliation. Here we utilize a facile and robust methodology to grow large-scale vertically aligned MoS$_2$ (VA-MoS$_2$) films on standard silicon substrates. Memristive devices with the structure silver/VA-MoS$_2$/Si are shown to have low set-ON voltages (<0.5V), large-retention times ($>2\times10^4$ s) and high thermal stability (up to 350 $^\circ$C). The proposed memristive device also exhibits long term potentiation / depression (LTP/LTD) and photo-active memory states. The large-scale fabrication, together with the low operating voltages, high thermal stability, light-responsive behaviour and long-term potentiation/depression, makes this approach very appealing for real-life non-volatile memory applications.