Independent-atom-model coupled-channel calculations strengthen the case for interatomic Coulomb decay as a subdominant reaction channel in slow O$^{3+}$-Ne$_2$ collisions

TL;DR

This study uses independent-atom-model coupled-channel calculations to analyze electron removal in slow O$^{3+}$-Ne$_2$ collisions, highlighting interatomic Coulomb decay as a minor reaction pathway supported by experimental data.

Contribution

It introduces a coupled-channel approach with orientation averaging to better understand electron removal processes in ion-dimer collisions, emphasizing interatomic Coulomb decay.

Findings

Agreement with experimental data for O$^{3+}$-Ne$_2$ with screened potential

Disagreement with data for Li$^{3+}$ with bare Coulomb potential

Interatomic Coulomb decay is a subdominant reaction channel

Abstract

We report on electron removal calculations for 2.81 keV/amu Li$^{3+}$ and O$^{3+}$ ion collisions with neon dimers. The target is described as two independent neon atoms fixed at the dimer's equilibrium bond length, whose electrons are subjected to the time-dependent bare and screened Coulomb potentials of the classically moving Li$^{3+}$ and O$^{3+}$ projectile ions, respectively. Three mutually perpendicular orientations of the dimer with respect to the rectilinear projectile trajectories are considered and collision events for the two ion-atom subsystems are combined in an impact parameter by impact parameter fashion and are orientation-averaged to calculate probabilities and cross sections for the ion-dimer system. The coupled-channel two-center basis generator method is used to solve the ion-atom collision problems. We concentrate the ion-dimer analysis on one-electron and two-electron removal processes which can be associated with interatomic Coulomb decay, Coulomb explosion, and radiative charge transfer. We find that the calculated relative yields are in fair agreement with recent experimental data for O$^{3+}$-Ne$_2$ collisions if we represent the projectile by a screened Coulomb potential, but disagree markedly for a bare Coulomb potential, i.e., for Li$^{3+}$ impact. In particular, our calculations suggest that interatomic Coulomb decay is a significant reaction channel in the former case only, since capture of a Ne($2s$) electron to form hydrogenlike Li$^{2+}$ is unlikely.