Glass theory: ground and excited states of coupled electron pairs
Jia Lin Wu

TL;DR
This paper introduces a novel coupled electron pair excited state model that explains glass transition phenomena through a new mathematical physics regime involving nano-scale dynamic Ising models.
Contribution
It presents a new theoretical framework for understanding glass states using coupled electron pairs and dynamic Ising models, extending Gennes' SODV theory.
Findings
Discovery of a synchronous-antisymmetric coupled electron pair excited state
Explanation of glass transition phenomena via nano-scale dynamic Ising models
Identification of a new regime with energy levels much lower than electronic excited states
Abstract
Since the discovery of the strict second-order-delta-vector (magnetic moment) (SODV) theory of Gennes n = 0, the theoretical community has been searching for SODVs that can evolve from complex glass states to biomolecular systems. In the theoretical study of the abnormal viscosity of entangled polymer melts, we unexpectedly found an SODV. It is a synchronous-antisymmetric coupled electron pair (CEP) excited state that creates a dynamic interface between two slightly overlapping adjacent hard-sphere molecules (HSMs). The two HSMs suddenly acquired the identical new spin in opposite directions, so the two-dimensional soft matrix predicted by de Gennes was found in the glass model. Unlike electronic excited states, the energy of CEP excited states is three orders of magnitude smaller than that of electronic excited states, and they appear in the form of a nano-scale dynamic Ising models.…
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Taxonomy
TopicsSpectroscopy and Quantum Chemical Studies · Photochemistry and Electron Transfer Studies · Advanced Thermodynamics and Statistical Mechanics
