Defect behavior and radiation tolerance of MAB phases (MoAlB and Fe2AlB2) with comparison to MAX phases

TL;DR

This study compares the defect behavior and radiation tolerance of MAB phases MoAlB and Fe2AlB2, revealing Fe2AlB2's superior radiation resistance and suggesting MAB phases as promising materials for radiation-exposed applications.

Contribution

It provides the first combined experimental and theoretical analysis of defect evolution and radiation tolerance in MAB phases, highlighting their potential for radiation-resistant applications.

Findings

Fe2AlB2 is more radiation-tolerant than MoAlB.

MAB phases have lower radiation tolerance than MAX phases but are comparable to SiC.

MAB phases do not exhibit radiation-induced cracking under irradiation.

Abstract

MAB phases are a new class of layered ternary materials that have already shown a number of outstanding properties. Here, we investigate defect evolution and radiation tolerance of two MAB phases, MoAlB and Fe2AlB2, using a combination of experimental characterization and first-principles calculations. We find that Fe2AlB2 is more tolerant to radiation-induced amorphization than MoAlB, both at 150 {\deg}C and at 300 {\deg}C. The results can be explained by the fact that the Mo Frenkel pair is unstable in MoAlB and as a result, irradiated MoAlB is expected to have a significant concentration of MoAl antisites, which are difficult to anneal even at 300 {\deg}C. We find that the tolerance to radiation-induced amorphization of MAB phases is lower than in MAX phases, but it is comparable to that of SiC. However, MAB phases do not show radiation-induced cracking which is observed in MAX phases under the same irradiation conditions. This study suggests that MAB phases might be a promising class of materials for applications that involve radiation.