Nonequilibrium master kinetic equation modelling of colloidal gelation

TL;DR

This paper develops an analytical kinetic model for colloidal gelation driven by critical Casimir forces, predicting cluster size distributions and phase transition behavior consistent with experiments and simulations.

Contribution

It introduces a master kinetic equation approach with single-particle detachment dominance, providing analytical predictions for gelation dynamics and critical exponents.

Findings

Power-law cluster size distributions with exponents -3/2 and -5/2

Largest cluster size diverges with percolation-like critical exponent

Gelation identified as a second-order nonequilibrium phase transition

Abstract

We present a detailed study of the kinetic cluster growth process during gelation of weakly attractive colloidal particles by means of experiments on critical Casimir attractive colloidal systems, simulations and analytical theory. In the experiments and simulations, we follow the mean coordination number of the particles during the growth of clusters to identify an attractive-strength independent cluster evolution as a function of mean coordination number. We relate this cluster evolution to the kinetic attachment and detachment rates of particles and particle clusters. We find that single-particle detachment dominates in the relevant weak attractive-strength regime, while association rates are almost independent of the cluster size. Using the limit of single-particle dissociation and size-independent association rates, we solve the master kinetic equation of cluster growth analytically to predict power-law cluster mass distributions with exponents $-3/2$ and $-5/2$ before and after gelation, respectively, which are consistent with the experimental and simulation data. These results suggest that the observed critical Casimir-induced gelation is a second-order nonequilibrium phase transition (with broken detailed balance). Consistent with this scenario, the size of the largest cluster is observed to diverge with power-law exponent according to three-dimensional percolation upon approaching the critical mean coordination number.