Sliding Over Graphene Grain Boundaries: A Step Towards Macroscale Superlubricity

TL;DR

This study investigates how grain boundaries in graphene affect frictional properties, revealing mechanisms that could enable macroscale superlubricity in graphitic contacts.

Contribution

It provides new insights into the frictional mechanisms at graphene grain boundaries, advancing understanding towards achieving macroscale superlubricity.

Findings

Friction varies with boundary misfit angle and surface corrugation.

Frictional energy dissipation involves defect buckling and elastic energy storage.

Friction dependence on normal load can be non-monotonic.

Abstract

In light of the race towards macroscale superlubricity of graphitic contacts, the effect of grain boundaries on their frictional properties becomes of central importance. Here, we elucidate the unique frictional mechanisms characterizing topological defects along typical grain boundaries that can vary from being nearly flat to highly corrugated, depending on the boundary misfit angle. We find that frictional energy dissipation over grain boundaries can originate from variations of compressibility along the surface, heat produced during defect (un)buckling events, and elastic energy storage in irreversible buckling processes. These may lead to atypical non-monotonic dependence of the averaged friction on the normal load. The knowledge gained in the present study constitutes an important step towards the realization of superlubricity in macroscopic graphitic contacts.